铃木彰

    铃木章是日本化学家和诺贝尔奖获得者,他于1979年首次发表了Suzuki反应,即芳基或乙烯基硼酸与芳基或乙烯基卤化物在钯(0)络合物催化下的有机反应。

铃木彰(Akira Suzuki)名言

The palladium-catalyzed cross-coupling reaction between different types of organoboron compounds and various organic electrophiles including halides or triflates in the presence of a base provides a powerful and general methodology for the formation of carbon-carbon bonds.

在碱的存在下,不同类型的有机硼化合物与各种有机亲电子试剂(包括卤化物或三氟甲磺酸酯)之间的钯催化交叉偶联反应为形成碳-碳键提供了强大而通用的方法。

铃木彰

The coupling of aryl halides with copper at very high temperature is called the Ullmann reaction, which is of broad scope and has been used to prepare many symmetrical biaryls. However, when a mixture of two different aryl halides is used, there are three possible biaryl products.

在非常高的温度下,芳基卤化物与铜的偶联称为Ullmann反应,该反应范围很广,已用于制备许多对称的联芳基。 然而,当使用两种不同的芳基卤化物的混合物时,存在三种可能的联芳基产物。

铃木彰

Carbon-carbon bond formation reactions employing organoboron compounds and organic electrophiles have recently been recognized as powerful tools for the construction of new organic compounds.

最近,使用有机硼化合物和有机亲电试剂的碳-碳键形成反应已被认为是构建新有机化合物的有力工具。

铃木彰